WebROH ROH + phMe B ROH+ .PhCH2Br Protects from: Bases and weak acids Formation : Methyl Ethers CH2N2 Mel. THF MezS0. Me,o BF, Cleavage : Benzyl Ethers BnBr. THF. NOH CF3s03H NalNHJ ... TsOH 75% JACS, 100, 1978, 14, 4620 CHO or Cleavage:Acid hydrolysis or hydrogenolysis CHO HO . WebNov 4, 2024 · 【详解】 ,与氢气发生加成反应生成,碳碳双键及酮基都发生了加成反应,所以1mol 反应生成E至少需要2mol氢气,故答案为:2; 试卷第22 页,总38 ,发生消去反应,生成,化学方程式为 TsOH PhMe O,故答案为:TsOH PhMe 试卷第23页,总38 (5)由G生成H分两步进行:反应1 ...
Synthesis and ring-chain-ring tautomerism of bisoxazolidines ...
WebGroup&Meeting&Problems& 22October2013& Anne&Kornahrens& Please&provide&plausible&mechanismsforthefollowingproblems,&providing&intermediates&or&anexplanationof& WebThis is an Accepted Manuscript, which has been through the Royal Society of Chemistry peer review process and has been accepted for publication. Accepted Manuscripts are … how do cheetahs attract a mate
US11505522B2 Processes for the preparation of (S)-tert-butyl 4,5 ...
WebNov 5, 2024 · Introduction. Shearinines G and D are complex indole diterpenoids from the Janthitrem class of natural products (Scheme 1).They were initially isolated from the … Webp-Toluenesulfonic acid monohydrate (p-TsOH·H 2 O) may be used as a catalyst in the synthesis of the following: Unsymmetrical benzils. Highly substituted piperidines. 1,3,5 … Web2. L-Selectride, PhMe 8. -78°C, 30min, then aq. NHCl, warming 10. from -78°C to 0°C 3. LAH, THF, rt, 12h, 94% OH Me OEt Me OEt 4. TsCl, Et3N, DMAP 5. KCN, DMSO 6. 1 M HCl 7. vinylMgBr Me Me HO 5 M HCl, 70°C 9. AD-mix-α TBDPSCl Me Me O OTBDPS OH O H Me Me O OTBDPS OH O H 11. DMP 12. NaBH4, MeOH 13. MPMOC(NH)CCl3 H TfOH Bundles … how do cheetahs find a mate